About Calcium ion energy storage
5,7,12,14-Pentacenetetrone (PT, 95% purity) was purchased from Macklin reagent Co., LTD. To prepare the PT anode, the PT material, acetylene black and polyvinylidene fluoride (PVDF) binder were mixed.
Three-electrode beaker cells were first assembled with as-prepared PT or KCoFe(CN)6 electrode (1 × 1 cm) as working electrode, Pt as the counter electrode and Ag.
Both CV experiment and GCD measurements was carried out on a CHI760E electrochemical workstation. GITT was performed using a battery testing system (LAND C.
The structure and phase composition were characterized by X-ray diffraction measurement (XRD, Rigaku D/max 2500/PC using CuKa radiation) and the diffraction data w.
DFT calculations with the PBE functional were performed by using the Vienna ab initio Simulation Package58,59. The electron–ion interactions were presented by the frozen core al.Calcium-ion batteries (CIBs) are a promising next-generation energy storage system given the low redox potential of calcium metal and high abundance of calcium compounds. For continued CIB development, the discovery of high energy density calcium ion cathodes is needed to achieve practical energy density values.
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