About High power dual ion energy storage battery
Graphite is typically used as an anode material in commercial Li-ion batteries, wherein it uptakes Li-ion (up to charge storage capacity of 372 mAh g−1). In the context of DIB, however, this material serves as the ca.
GDIB works as a non-rocking-chair, i.e. dual-ion battery by utilizing the reversible intercalation of anions into the graphite cathode during charging (oxidation of graphite network).
Generally, the solubility of a salt is determined by the lattice energy (the energy cost to overcome to form separate ions from the crystal lattice) and solvation energy of ions (th.
To better understand the staging mechanism of FSI− anion intercalation into graphite, DFT calculations were performed. Complex anion species do not insert evenly into every graphit.
Following the computational studies, the staging mechanism of FSI− anion intercalation into graphite was experimentally probed by in situ XRD measurements. F.
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